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- W2997521664 abstract "Non-Newtonian fluids are ubiquitous in daily life and industrial applications. Herein, we report an intelligent fluidic system integrating two distinct non-Newtonian rheological properties mediated by an autocatalytic enzyme reaction. Associative polyelectrolytes bearing a small amount of ionic and alkyl groups are engineered: by carefully balancing the charge density and the hydrophobic effect, the polymer solutions demonstrate a unique shear thickening property at low pH while shear thinning at high pH. The urea-urease clock reaction is utilized to program a feedback-induced pH change, leading to a strong upturn of the nonlinear viscoelastic properties. As long as the chemical fuel is supplied, two distinct non-Newtonian states can be achieved with a tunable lifetime span. As a proof of concept, we demonstrate how the physical energy-driven nonequilibrium properties can be manipulated by a chemical-fueled process." @default.
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- W2997521664 date "2020-01-29" @default.
- W2997521664 modified "2023-09-29" @default.
- W2997521664 title "Biocatalytic Feedback‐Controlled Non‐Newtonian Fluids" @default.
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- W2997521664 doi "https://doi.org/10.1002/anie.201914398" @default.
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