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- W2997751392 abstract "In the context of efforts to develop at the same time high energy density cathode materials for lithium-ion batteries with low content of critical elements such as cobalt and new cell chemistries for all-solid-state batteries, a novel family of lithium-rich layered sulfides (Li[LitTi1-t]S2, 0 < t ≤ 0.33) belonging to the LiTiS2 – Li2TiS3 system was investigated as intercalation materials. These sulfides, in which both cations and anions are involved in the redox process, display common features with isotype Li-rich layered oxides (Li[LixM1-x]O2, M = Mn, Ni, Co, …). In a particular composition range, they exhibit high electrochemical performance with a reversible capacity and an energy density exceeding respectively 265 mAh·g-1 and 600 Wh·kg-1, a very low irreversible capacity in the first cycle, fast activation and a limited voltage decay. Their operation potential within the electrochemical stability window of sulfide-based fast ionic conductors makes them promising cathode materials for all-solid-state lithium and Li-ion batteries." @default.
- W2997751392 created "2020-01-10" @default.
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- W2997751392 date "2020-04-01" @default.
- W2997751392 modified "2023-10-18" @default.
- W2997751392 title "Lithium-rich layered titanium sulfides: Cobalt- and Nickel-free high capacity cathode materials for lithium-ion batteries" @default.
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- W2997751392 doi "https://doi.org/10.1016/j.ensm.2019.12.033" @default.
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