FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2998384404> ?p ?o ?g. }

• W2998384404 endingPage "307" @default.
• W2998384404 startingPage "287" @default.
• W2998384404 abstract "SbPO4 is a complex monoclinic layered material characterized by a strong activity of the nonbonding lone electron pair (LEP) of Sb. The strong cation LEP leads to the formation of layers piled up along the a axis and linked by weak Sb–O electrostatic interactions. In fact, Sb has 4-fold coordination with O similarly to what occurs with the P–O coordination, despite the large difference in ionic radii and electronegativity between both elements. Here we report a joint experimental and theoretical study of the structural and vibrational properties of SbPO4 at high pressure. We show that SbPO4 is not only one of the most compressible phosphates but also one of the most compressible compounds of the ABO4 family. Moreover, it has a considerable anisotropic compression behavior, with the largest compression occurring along a direction close to the a axis and governed by the compression of the LEP and the weak interlayer Sb–O bonds. The strong compression along the a axis leads to a subtle modification of the monoclinic crystal structure above 3 GPa, leading from a 2D to a 3D material. Moreover, the onset of a reversible pressure-induced phase transition is observed above 9 GPa, which is completed above 20 GPa. We propose that the high-pressure phase is a triclinic distortion of the original monoclinic phase. The understanding of the compression mechanism of SbPO4 can aid to improve the ion intercalation and catalytic properties of this layered compound." @default.
• W2998384404 created "2020-01-10" @default.
• W2998384404 creator A5005767222 @default.
• W2998384404 creator A5009379833 @default.
• W2998384404 creator A5010022844 @default.
• W2998384404 creator A5011908816 @default.
• W2998384404 creator A5013623035 @default.
• W2998384404 creator A5020504941 @default.
• W2998384404 creator A5032015888 @default.
• W2998384404 creator A5044928632 @default.
• W2998384404 creator A5049357016 @default.
• W2998384404 creator A5058162171 @default.
• W2998384404 creator A5059024436 @default.
• W2998384404 creator A5061290933 @default.
• W2998384404 creator A5065811119 @default.
• W2998384404 creator A5072808634 @default.
• W2998384404 creator A5081023386 @default.
• W2998384404 creator A5086768178 @default.
• W2998384404 creator A5088363600 @default.
• W2998384404 date "2019-12-26" @default.
• W2998384404 modified "2023-10-18" @default.
• W2998384404 title "Experimental and Theoretical Study of SbPO₄ under Compression" @default.
• W2998384404 cites W1531219050 @default.
• W2998384404 cites W1573782868 @default.
• W2998384404 cites W1747553609 @default.
• W2998384404 cites W1965793782 @default.
• W2998384404 cites W1969156767 @default.
• W2998384404 cites W1969638099 @default.
• W2998384404 cites W1970127494 @default.
• W2998384404 cites W1973376695 @default.
• W2998384404 cites W1974968342 @default.
• W2998384404 cites W1980223044 @default.
• W2998384404 cites W1981247431 @default.
• W2998384404 cites W1981796441 @default.
• W2998384404 cites W1995451768 @default.
• W2998384404 cites W1995784089 @default.
• W2998384404 cites W1997126459 @default.
• W2998384404 cites W1998981899 @default.
• W2998384404 cites W2006707423 @default.
• W2998384404 cites W2008306992 @default.
• W2998384404 cites W2008319486 @default.
• W2998384404 cites W2016168218 @default.
• W2998384404 cites W2020765898 @default.
• W2998384404 cites W2028056984 @default.
• W2998384404 cites W2030054819 @default.
• W2998384404 cites W2030976617 @default.
• W2998384404 cites W2035426615 @default.
• W2998384404 cites W2036113194 @default.
• W2998384404 cites W2044675786 @default.
• W2998384404 cites W2046015601 @default.
• W2998384404 cites W2048885352 @default.
• W2998384404 cites W2052410207 @default.
• W2998384404 cites W2055144391 @default.
• W2998384404 cites W2055796707 @default.
• W2998384404 cites W2065141150 @default.
• W2998384404 cites W2066030435 @default.
• W2998384404 cites W2066263948 @default.
• W2998384404 cites W2068994203 @default.
• W2998384404 cites W2077137667 @default.
• W2998384404 cites W2077904762 @default.
• W2998384404 cites W2078321088 @default.
• W2998384404 cites W2079105963 @default.
• W2998384404 cites W2079304910 @default.
• W2998384404 cites W2082361107 @default.
• W2998384404 cites W2084296818 @default.
• W2998384404 cites W2086539192 @default.
• W2998384404 cites W2090001718 @default.
• W2998384404 cites W2094670958 @default.
• W2998384404 cites W2126449292 @default.
• W2998384404 cites W2168936212 @default.
• W2998384404 cites W2185736113 @default.
• W2998384404 cites W2313354922 @default.
• W2998384404 cites W2316451076 @default.
• W2998384404 cites W2321581198 @default.
• W2998384404 cites W2327374357 @default.
• W2998384404 cites W2333150609 @default.
• W2998384404 cites W2340551661 @default.
• W2998384404 cites W2343774618 @default.
• W2998384404 cites W2464519160 @default.
• W2998384404 cites W2479057198 @default.
• W2998384404 cites W2540212894 @default.
• W2998384404 cites W2544949061 @default.
• W2998384404 cites W2561368924 @default.
• W2998384404 cites W2563923062 @default.
• W2998384404 cites W2577728878 @default.
• W2998384404 cites W2593962029 @default.
• W2998384404 cites W2747525247 @default.
• W2998384404 cites W2770680658 @default.
• W2998384404 cites W2772199295 @default.
• W2998384404 cites W2772773756 @default.
• W2998384404 cites W2786880113 @default.
• W2998384404 cites W2795228825 @default.
• W2998384404 cites W2795770134 @default.
• W2998384404 cites W2800478085 @default.
• W2998384404 cites W2801096717 @default.
• W2998384404 cites W2808815838 @default.
• W2998384404 cites W2883671349 @default.
• W2998384404 cites W2885049329 @default.

• next