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• W2998484072 abstract "The separation of short-chained alkanes and alkenes is challenging because of their chemical similarity and thus being costly in energy. The implementation of a cryogenic adsorption process may overcome this problem, but systematic studies on light hydrocarbon adsorption at low temperatures are virtually lacking. Therefore, as a first step, in this paper, we present single-component adsorption isotherms of ethane, ethylene, propane, and propylene on activated carbon (AC) and zeolite 13X for temperatures of −80 to +20 °C and partial pressures of 5–1250 Pa. Based on these experimental data, the interactions of the adsorptives with the chemically different surfaces and their temperature dependence are discussed. Results show a strong increase in capacity with decreasing temperature for both AC and zeolite 13X. Cryogenic adsorption increases the overall (calculated) selectivity of alkane–alkene separation, especially for the zeolite 13X." @default.
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• W2998484072 date "2020-01-02" @default.
• W2998484072 modified "2023-10-14" @default.
• W2998484072 title "Adsorption of Light Alkanes and Alkenes on Activated Carbon and Zeolite 13X at Low Temperatures" @default.
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• W2998484072 doi "https://doi.org/10.1021/acs.jced.9b00948" @default.
• W2998484072 hasPublicationYear "2020" @default.
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