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- W2998565567 abstract "A method for the synthesis of 2-carboxy-5,6-ethylenedioxyindole and its 4- and 7-chloro derivatives from 3,4-ethylenedioxyaniline and, correspondingly, its 2- and 5-chloro derivatives via the Fischer reaction was developed. It was established that in the case of bromination or chlorination under mild conditions 2-carbethoxy-5,6-ethylenedioxyindole forms 3-halo derivatives, while 5,6-ethylenedioxyindole itself forms only 3,7-dihalo derivatives. The closeness in the reactivities of the 3 and 7 ring positions of 5,6-ethylenedioxyindole (as compared with indole) is in agreement with the results of calculations of the quantum-chemical reactivity indexes for electrophilic substitution." @default.
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- W2998565567 date "1983-02-22" @default.
- W2998565567 modified "2023-09-24" @default.
- W2998565567 title "ChemInform Abstract: SYNTHESIS OF 2-CARBOXY-5,6-ETHYLENEDIOXYINDOLE AND ITS 3-, 4-, AND 7-HALO DERIVATIVES" @default.
- W2998565567 doi "https://doi.org/10.1002/chin.198308236" @default.
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