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- W2998877393 abstract "A new application of hydroxylamine‐ O ‐sulfonic acid (HOSA) has been discovered whereby aromatic ketones react with HOSA and alkynes to form isoquinolines in the presence of a Rh III catalyst. This C–H/N–O annulation methodology gives excellent yields even without any silver additive, acid/base or metal oxidant. This is the first report wherein a directing group is simultaneously forming in situ, acting as acid additive, and also as an internal oxidant." @default.
- W2998877393 created "2020-01-23" @default.
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- W2998877393 date "2020-02-05" @default.
- W2998877393 modified "2023-10-07" @default.
- W2998877393 title "Hydroxylamine‐<i>O</i>‐Sulfonic Acid (HOSA) as a Redox‐Neutral Directing Group: Rhodium Catalyzed, Additive Free, One‐Pot Synthesis of Isoquinolines from Arylketones" @default.
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- W2998877393 doi "https://doi.org/10.1002/ejoc.201901825" @default.
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