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- W2999013551 abstract "Protons at the water/vapor interface are relevant for atmospheric and environmental processes, yet characterizing their surface affinity on the quantitative level is still challenging. Here we utilize phase-sensitive sum-frequency vibrational spectroscopy to quantify the surface density of protons (or their hydronium form) at the intrinsic water/vapor interface through inspecting the surface-field-induced alignment of water molecules in the electrical double layer of ions. With hydrogen halides in water, the surface adsorption of protons is found to be independent of specific proton-halide anion interactions and to follow a constant adsorption free energy, ΔG ≈ -3.76 (±0.79) kJ/mol, corresponding to a partitioning coefficient of the surface with respect to bulk water by 3.3∼6.2, for bulk ion concentrations up to 0.3 M. Our spectroscopic study not only is of importance in atmospheric chemistry but also offers a microscopic-level basis to develop advanced quantum-mechanical models for molecular simulations." @default.
- W2999013551 created "2020-01-23" @default.
- W2999013551 creator A5042198322 @default.
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- W2999013551 date "2020-01-09" @default.
- W2999013551 modified "2023-10-17" @default.
- W2999013551 title "Affinity of Hydrated Protons at Intrinsic Water/Vapor Interface Revealed by Ion-Induced Water Alignment" @default.
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- W2999013551 doi "https://doi.org/10.1021/acs.jpclett.9b03520" @default.
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