Matches in SemOpenAlex for { <https://semopenalex.org/work/W2999697594> ?p ?o ?g. }
- W2999697594 endingPage "3151" @default.
- W2999697594 startingPage "3143" @default.
- W2999697594 abstract "Investigating the structure of active ingredients, such as agrochemicals and their associated metabolites, is a crucial requisite in the discovery and development of these molecules. In this study, structural characterization by electron-induced dissociation (EID) was compared to collisionally activated dissociation (CAD) on a series of agrochemicals. EID fragmentation produced a greater variety of fragment ions and complementary ion pairs leading to more complete functional group characterization compared to CAD. The results obtained displayed many more cross-ring fragmentation of the pyrimidine ring compared to the pyridine ring. Compounds that consisted of one aromatic heterocyclic moiety (azoxystrobin, fluazifop acid, fluazifop-p-butyl, and pirimiphos-methyl) displayed cross-ring fragmentation while compounds with only aromatic hydrocarbon rings (fenpropidin and S-metolachlor) displayed no cross-ring fragmentation. The advantages of high-resolution accurate mass spectrometry (HRAM MS) are shown with the majority of assignments at ppb range error values and the ability to differentiate ions with the same nominal mass but different elemental composition. This highlights the potential for HRAM MS and EID to be used as a tool for structural characterization of small molecules with a wide variety of functional groups and structural motifs." @default.
- W2999697594 created "2020-01-23" @default.
- W2999697594 creator A5000997975 @default.
- W2999697594 creator A5012690069 @default.
- W2999697594 creator A5016267640 @default.
- W2999697594 creator A5018475409 @default.
- W2999697594 creator A5021528836 @default.
- W2999697594 creator A5034525241 @default.
- W2999697594 creator A5068511896 @default.
- W2999697594 creator A5089720671 @default.
- W2999697594 date "2020-01-07" @default.
- W2999697594 modified "2023-09-29" @default.
- W2999697594 title "Comparison of Fragmentation Techniques for the Structural Characterization of Singly Charged Agrochemicals" @default.
- W2999697594 cites W1231945058 @default.
- W2999697594 cites W1778316999 @default.
- W2999697594 cites W1896477328 @default.
- W2999697594 cites W1969418515 @default.
- W2999697594 cites W1970325088 @default.
- W2999697594 cites W1981714164 @default.
- W2999697594 cites W1982119775 @default.
- W2999697594 cites W1992911600 @default.
- W2999697594 cites W1995360951 @default.
- W2999697594 cites W1999101000 @default.
- W2999697594 cites W2007891542 @default.
- W2999697594 cites W2014056093 @default.
- W2999697594 cites W2019330498 @default.
- W2999697594 cites W2024867228 @default.
- W2999697594 cites W2026429638 @default.
- W2999697594 cites W2027107189 @default.
- W2999697594 cites W2029537579 @default.
- W2999697594 cites W2035796114 @default.
- W2999697594 cites W2036186000 @default.
- W2999697594 cites W2048527293 @default.
- W2999697594 cites W2054023813 @default.
- W2999697594 cites W2054110970 @default.
- W2999697594 cites W2054686401 @default.
- W2999697594 cites W2055036923 @default.
- W2999697594 cites W2063437403 @default.
- W2999697594 cites W2065484278 @default.
- W2999697594 cites W2068926428 @default.
- W2999697594 cites W2069031182 @default.
- W2999697594 cites W2069348426 @default.
- W2999697594 cites W2073819168 @default.
- W2999697594 cites W2074877005 @default.
- W2999697594 cites W2077644068 @default.
- W2999697594 cites W2077748277 @default.
- W2999697594 cites W2080991324 @default.
- W2999697594 cites W2086786189 @default.
- W2999697594 cites W2093201171 @default.
- W2999697594 cites W2094435688 @default.
- W2999697594 cites W2095302031 @default.
- W2999697594 cites W2102514859 @default.
- W2999697594 cites W2119960756 @default.
- W2999697594 cites W2129829662 @default.
- W2999697594 cites W2130757825 @default.
- W2999697594 cites W2134200851 @default.
- W2999697594 cites W2142326039 @default.
- W2999697594 cites W2158847414 @default.
- W2999697594 cites W2159493635 @default.
- W2999697594 cites W2209860516 @default.
- W2999697594 cites W2281529082 @default.
- W2999697594 cites W2312968377 @default.
- W2999697594 cites W2313263360 @default.
- W2999697594 cites W2323904653 @default.
- W2999697594 cites W2326047051 @default.
- W2999697594 cites W2394489651 @default.
- W2999697594 cites W2506935231 @default.
- W2999697594 cites W2574994168 @default.
- W2999697594 cites W2582163239 @default.
- W2999697594 cites W2610737038 @default.
- W2999697594 cites W2747896873 @default.
- W2999697594 cites W2889520719 @default.
- W2999697594 cites W793735389 @default.
- W2999697594 doi "https://doi.org/10.1021/acs.analchem.9b04820" @default.
- W2999697594 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31909982" @default.
- W2999697594 hasPublicationYear "2020" @default.
- W2999697594 type Work @default.
- W2999697594 sameAs 2999697594 @default.
- W2999697594 citedByCount "8" @default.
- W2999697594 countsByYear W29996975942020 @default.
- W2999697594 countsByYear W29996975942021 @default.
- W2999697594 countsByYear W29996975942022 @default.
- W2999697594 countsByYear W29996975942023 @default.
- W2999697594 crossrefType "journal-article" @default.
- W2999697594 hasAuthorship W2999697594A5000997975 @default.
- W2999697594 hasAuthorship W2999697594A5012690069 @default.
- W2999697594 hasAuthorship W2999697594A5016267640 @default.
- W2999697594 hasAuthorship W2999697594A5018475409 @default.
- W2999697594 hasAuthorship W2999697594A5021528836 @default.
- W2999697594 hasAuthorship W2999697594A5034525241 @default.
- W2999697594 hasAuthorship W2999697594A5068511896 @default.
- W2999697594 hasAuthorship W2999697594A5089720671 @default.
- W2999697594 hasConcept C102931765 @default.
- W2999697594 hasConcept C111919701 @default.
- W2999697594 hasConcept C178790620 @default.
- W2999697594 hasConcept C185592680 @default.
- W2999697594 hasConcept C191015642 @default.
- W2999697594 hasConcept C2776568683 @default.