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- W3000060275 abstract "A simple chiral binuclear titanium complex ((S)-Ti2L3Na4) was first prepared and served as an excellent chiral sensor for discriminating a variety of chiral ammoniums by 1H NMR. In the presence of trifluoroacetic acid, the in-situ-generated ammoniums of varied amines can be effectively resolved by (S)-Ti2L3Na4. The different binding forces between (S)-Ti2L3Na4 and two enantiomers of analytes generate different shielding effects on two enantiomers, resulting in a split in the distinguishable chemical shift." @default.
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- W3000060275 date "2020-01-08" @default.
- W3000060275 modified "2023-09-25" @default.
- W3000060275 title "Chiral Discrimination of Varied Ammonium Compounds through <sup>1</sup>H NMR Using a Binuclear Ti Complex Sensor" @default.
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- W3000060275 doi "https://doi.org/10.1021/acs.orglett.9b04373" @default.
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