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- W3000071888 abstract "In this study, the effects of Ag+ (140 mg/L) in an electrolyte on the oxygen evolution and corrosion behaviors of Pb and PbAg (0.6 wt%) anodes in diaphragm electrolysis were investigated by utilizing a variety of tests and analyses, including galvanostatic polarization, mass increment, ion concentration, anodic polarization curve, phase analysis, and scanning electron microscopy of the oxide layer and substrate. The results show that an ion exchange membrane can effectively prevent Ag+ and Pb2+ from penetrating into the cathode chamber and depositing on the cathode. The addition of Ag+ in diaphragm electrolysis significantly lowers the overpotential of oxygen evolution reaction and improves the corrosion resistance of Pb and PbAg (0.6 wt%) anodes. This is mainly attributed to the formation of Ag2O2 on the surface of the anode, which provides good catalytic activity for the oxygen evolution reaction (Ag2O2 can form Ag2O2 hydrate in sulfuric acid solution, Ag2O2 hydrate loses electrons and H+ during electrification, and then Ag2O2 is formed again after electron rearrangement)." @default.
- W3000071888 created "2020-01-23" @default.
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- W3000071888 date "2020-03-01" @default.
- W3000071888 modified "2023-10-15" @default.
- W3000071888 title "Effects of Ag+ in diaphragm electrolysis on oxygen evolution and corrosion behaviors of Pb and Pb Ag anodes" @default.
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- W3000071888 doi "https://doi.org/10.1016/j.hydromet.2020.105254" @default.
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