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• W3000087997 startingPage "222" @default.
• W3000087997 abstract "Hyperbranched polyoxetanes are a relatively new class of polymers. These are branched polyethers that are synthesized from oxetanes—four-member cyclic ethers bearing hydroxymethyl groups—via ring-opening polymerization. Four series of polyoxetanes were synthesized from 3-ethyl-3-(hydroxymethyl)oxetane and 1,1,1-tris(hydroxymethyl)propane as a core molecule. Reagents ratios ranged from 1:5 to 1:50, theoretical molar mass ranged from 714 g/mol to 5942 g/mol, and dispersities ranged from 1.77 to 3.75. The morphology of the macromolecules was investigated by a matrix-assisted laser desorption/ionization time of flight technique. The polyoxetanes’ adhesive interactions with polar materials were analyzed and provided results as follows: the work of adhesion was 101–105 mJ/m2, the bond-line tensile shear strengths were 0.39–1.32 MPa, and there was a brittle fracture mode within the polymer. The findings confirmed a good adhesion to polar substrates, but further research on polyoxetane modifications toward a reduction of brittleness is necessary." @default.
• W3000087997 created "2020-01-23" @default.
• W3000087997 creator A5057852890 @default.
• W3000087997 creator A5075061761 @default.
• W3000087997 date "2020-01-16" @default.
• W3000087997 modified "2023-09-24" @default.
• W3000087997 title "Poly-(3-ethyl-3-hydroxymethyl)oxetanes—Synthesis and Adhesive Interactions with Polar Substrates" @default.
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• W3000087997 doi "https://doi.org/10.3390/polym12010222" @default.
• W3000087997 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7023514" @default.
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