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• W3000195384 abstract "Structural design and/or carbon modification are the most important strategies to improve the performance of materials in many applications, where metal (oxide)-based anode design attracts great attention in metal ion batteries due to their high capacities. However, achieving these two goals within one-step remains challenging due to the lower cost and higher efficiency needed to satisfy the demand in practical application. Herein, we report a new approach for the crystal reconstruction of metal oxides by acetylene treatment, in which a hierarchical binary oxide decorated with carbon (i.e., Mn2Mo3O8@C) is introduced. The mechanism of constructing unique monocrystalline hexagonal nanoplates and uniform carbon coating is discussed in detail. Benefiting from the uniqueness of structure and composition, the Mn2Mo3O8@C demonstrates an extremely high lithium storage capacity of 890 mA h g-1 and good rate capacities at 20 A g-1 over 1000 cycles. In addition, the high rate capabilities and long cycle lifespan are further confirmed when the Mn2Mo3O8@C anode is matched with the nickel-rich layered oxide cathode. This study not only introduces a new binary oxide anode with high performances in lithium (ion) batteries but also presents a convenient methodology to design more advanced functional materials." @default.
• W3000195384 created "2020-01-23" @default.
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• W3000195384 date "2020-01-01" @default.
• W3000195384 modified "2023-10-17" @default.
• W3000195384 title "Crystal reconstruction of binary oxide hexagonal nanoplates: monocrystalline formation mechanism and high rate lithium-ion battery applications" @default.
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• W3000195384 doi "https://doi.org/10.1039/c9nr10032f" @default.
• W3000195384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32048679" @default.
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