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• W3000238701 endingPage "6073" @default.
• W3000238701 startingPage "6068" @default.
• W3000238701 abstract "Abstract We present a facile approach to encapsulate functional porous organic cages (POCs) into a robust MOF by an incipient‐wetness impregnation method. Porous cucurbit[6]uril (CB6) cages with high CO 2 affinity were successfully encapsulated into the nanospace of Cr‐based MIL‐101 while retaining the crystal framework, morphology, and high stability of MIL‐101. The encapsulated CB6 amount is controllable. Importantly, as the CB6 molecule with intrinsic micropores is smaller than the inner mesopores of MIL‐101, more affinity sites for CO 2 are created in the resulting CB6@MIL‐101 composites, leading to enhanced CO 2 uptake capacity and CO 2 /N 2 , CO 2 /CH 4 separation performance at low pressures. This POC@MOF encapsulation strategy provides a facile route to introduce functional POCs into stable MOFs for various potential applications." @default.
• W3000238701 created "2020-01-23" @default.
• W3000238701 creator A5002141451 @default.
• W3000238701 creator A5053735989 @default.
• W3000238701 creator A5058188634 @default.
• W3000238701 creator A5068725039 @default.
• W3000238701 creator A5069457681 @default.
• W3000238701 creator A5078414235 @default.
• W3000238701 creator A5090644272 @default.
• W3000238701 date "2020-02-03" @default.
• W3000238701 modified "2023-10-16" @default.
• W3000238701 title "Encapsulation of a Porous Organic Cage into the Pores of a Metal–Organic Framework for Enhanced CO₂ Separation" @default.
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