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• W3000279074 abstract "α-Galactosylceramide (α-GalCer) is recognized by the CD1d proteins on antigen-presenting cells at the ceramide moiety and the galactose moiety is presented to iNKT cells, which stimulates the immune responses. However, the immune suppression by repeated injections of α-GalCer has discouraged its development as an anti-cancer agent. To overcome the shortcoming by spatiotemporal restriction of its exposure, we synthesized the photochromic azobenzene-incorporated analogues and tested the photo-immunoregulation effect in its binding to CD1d. FACS analyses indicated that some of these analogues enhanced the affinity to CD1d on photo-irradiation by about 20%. A docking simulation suggests that the photochromic molecule should be bulkier for a clearer discrimination between on and off states." @default.
• W3000279074 created "2020-01-23" @default.
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• W3000279074 date "2020-03-01" @default.
• W3000279074 modified "2023-09-26" @default.
• W3000279074 title "Photo effect on the CD1d-binding ability of azobenzene-attached analogues of α-GalCer" @default.
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• W3000279074 doi "https://doi.org/10.1016/j.bmcl.2020.126960" @default.
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