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- W3000360280 abstract "A self-assembled G-quadruplex formed by guanosine and borate as the chiral scaffold was used to catalyze the asymmetric Friedel–Crafts reaction in water. Catalysis, depending on the self-assembly of guanosine and borate into a fibrillar structure in the presence of Cu2+ ions, can be modulated by the assembly concentration, temperature, and amount of Cu2+ ions. Detailed spectral experiments proved that the guanosine-based assembly in solution was responsible for the enantioselective catalysis, rather than small-molecule species. Some of the similar G-quartet assemblies were unable to promote the asymmetric reaction, implying unique properties of the current system, including excellent lifetime stability and supramolecular chiral structures. This work provided the first example of the self-assembled G-quadruplex achieving enantioselective catalysis and some perspective to better understand the design of nucleoside-based self-assemblies for an enantioselective reaction. In view of guanosine as a building block, these findings may be applied to discuss the prebiotic chiral catalyst preceded ribozymes." @default.
- W3000360280 created "2020-01-23" @default.
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- W3000360280 date "2020-01-14" @default.
- W3000360280 modified "2023-10-14" @default.
- W3000360280 title "Guanosine-Based Self-Assembly as an Enantioselective Catalyst Scaffold" @default.
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- W3000360280 doi "https://doi.org/10.1021/acs.joc.9b02718" @default.
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