Matches in SemOpenAlex for { <https://semopenalex.org/work/W3000402482> ?p ?o ?g. }
- W3000402482 endingPage "82" @default.
- W3000402482 startingPage "82" @default.
- W3000402482 abstract "Alkali earth metal molybdates (MMoO4, M = Mg, Ca, Sr, and Ba) were investigated as catalysts for the selective oxidation of methanol to formaldehyde in the search for more stable alternatives to the current industrial iron molybdate catalyst. The catalysts were prepared by either sol-gel synthesis or co-precipitation with both stoichiometric ratio (Mo:M = 1.0) and 10 mol% to 20 mol% excess Mo (Mo:M = 1.1 to 1.2). The catalysts were characterized by X-ray diffraction (XRD), nitrogen physisorption, Raman spectroscopy, temperature programmed desorption of CO2 (CO2-TPD), and inductively coupled plasma (ICP). The catalytic performance of the catalysts was measured in a lab-scale, packed bed reactor setup by continuous operation for up to 100 h on stream at 400 °C. Initial selectivities towards formaldehyde of above 97% were achieved for all samples with excess molybdenum oxide at MeOH conversions between 5% and 75%. Dimethyl ether (DME) and dimethoxymethane (DMM) were the main byproducts, but CO (0.1%–2.1%) and CO2 (0.1%–0.4%) were also detected. It was found that excess molybdenum oxide evaporated from all the catalysts under operating conditions within 10 to 100 h on stream. No molybdenum evaporation past the point of stoichiometry was detected." @default.
- W3000402482 created "2020-01-23" @default.
- W3000402482 creator A5010586732 @default.
- W3000402482 creator A5045620900 @default.
- W3000402482 creator A5050803413 @default.
- W3000402482 creator A5073327803 @default.
- W3000402482 creator A5076649877 @default.
- W3000402482 creator A5079607544 @default.
- W3000402482 creator A5085930816 @default.
- W3000402482 date "2020-01-06" @default.
- W3000402482 modified "2023-10-16" @default.
- W3000402482 title "Alkali Earth Metal Molybdates as Catalysts for the Selective Oxidation of Methanol to Formaldehyde—Selectivity, Activity, and Stability" @default.
- W3000402482 cites W1596090805 @default.
- W3000402482 cites W1656282237 @default.
- W3000402482 cites W1970299970 @default.
- W3000402482 cites W1974061729 @default.
- W3000402482 cites W1975175635 @default.
- W3000402482 cites W1985885292 @default.
- W3000402482 cites W1990530417 @default.
- W3000402482 cites W1997675278 @default.
- W3000402482 cites W1997701220 @default.
- W3000402482 cites W1998224751 @default.
- W3000402482 cites W1999781703 @default.
- W3000402482 cites W2013076977 @default.
- W3000402482 cites W2021336675 @default.
- W3000402482 cites W2023810814 @default.
- W3000402482 cites W2024199029 @default.
- W3000402482 cites W2026669235 @default.
- W3000402482 cites W2029536589 @default.
- W3000402482 cites W2029967155 @default.
- W3000402482 cites W2031096594 @default.
- W3000402482 cites W2032566559 @default.
- W3000402482 cites W2036352797 @default.
- W3000402482 cites W2037464628 @default.
- W3000402482 cites W2041425567 @default.
- W3000402482 cites W2043738016 @default.
- W3000402482 cites W2044734678 @default.
- W3000402482 cites W2054198305 @default.
- W3000402482 cites W2055545157 @default.
- W3000402482 cites W2067144071 @default.
- W3000402482 cites W2075919132 @default.
- W3000402482 cites W2079519319 @default.
- W3000402482 cites W2082543228 @default.
- W3000402482 cites W2085667868 @default.
- W3000402482 cites W2132636900 @default.
- W3000402482 cites W2139705150 @default.
- W3000402482 cites W2145875123 @default.
- W3000402482 cites W2146588336 @default.
- W3000402482 cites W2147045119 @default.
- W3000402482 cites W2168036365 @default.
- W3000402482 cites W2304631279 @default.
- W3000402482 cites W2330083722 @default.
- W3000402482 cites W2334207925 @default.
- W3000402482 cites W2527601161 @default.
- W3000402482 cites W2527723180 @default.
- W3000402482 cites W2609022200 @default.
- W3000402482 cites W2766044140 @default.
- W3000402482 cites W2802587418 @default.
- W3000402482 cites W2883860193 @default.
- W3000402482 cites W2908029600 @default.
- W3000402482 cites W2922167439 @default.
- W3000402482 cites W2952773737 @default.
- W3000402482 cites W3107483042 @default.
- W3000402482 cites W4255051879 @default.
- W3000402482 doi "https://doi.org/10.3390/catal10010082" @default.
- W3000402482 hasPublicationYear "2020" @default.
- W3000402482 type Work @default.
- W3000402482 sameAs 3000402482 @default.
- W3000402482 citedByCount "14" @default.
- W3000402482 countsByYear W30004024822020 @default.
- W3000402482 countsByYear W30004024822021 @default.
- W3000402482 countsByYear W30004024822022 @default.
- W3000402482 countsByYear W30004024822023 @default.
- W3000402482 crossrefType "journal-article" @default.
- W3000402482 hasAuthorship W3000402482A5010586732 @default.
- W3000402482 hasAuthorship W3000402482A5045620900 @default.
- W3000402482 hasAuthorship W3000402482A5050803413 @default.
- W3000402482 hasAuthorship W3000402482A5073327803 @default.
- W3000402482 hasAuthorship W3000402482A5076649877 @default.
- W3000402482 hasAuthorship W3000402482A5079607544 @default.
- W3000402482 hasAuthorship W3000402482A5085930816 @default.
- W3000402482 hasBestOaLocation W30004024821 @default.
- W3000402482 hasConcept C144082473 @default.
- W3000402482 hasConcept C161790260 @default.
- W3000402482 hasConcept C178790620 @default.
- W3000402482 hasConcept C179104552 @default.
- W3000402482 hasConcept C185592680 @default.
- W3000402482 hasConcept C2775930285 @default.
- W3000402482 hasConcept C2775981058 @default.
- W3000402482 hasConcept C2779028575 @default.
- W3000402482 hasConcept C2779607525 @default.
- W3000402482 hasConcept C549387045 @default.
- W3000402482 hasConceptScore W3000402482C144082473 @default.
- W3000402482 hasConceptScore W3000402482C161790260 @default.
- W3000402482 hasConceptScore W3000402482C178790620 @default.
- W3000402482 hasConceptScore W3000402482C179104552 @default.
- W3000402482 hasConceptScore W3000402482C185592680 @default.
- W3000402482 hasConceptScore W3000402482C2775930285 @default.