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• W3000412301 abstract "Abstract The 2D coordination polymer of Cu(II), [Cu(5-aip) (3-pic)2]n (5-aip = 5-aminoisophthalato, 3-pic = 3-picoline) was characterized by elemental analysis, FT-IR and UV–Vis spectroscopy and single crystal XRD techniques. The X-ray single crystal data revealed that the polymeric coordination complex crystallizes in the monoclinic system with P21/n space group and Cu(II) ion has five (square pyramidal) coordination number. X-ray diffraction analysis show that Cu(II) has a distorted square pyramidal geometry with τ = (175.75–160.0)/60) = 0.2625. Hirshfeld surface analysis was carried out, which reveals the nature of intermolecular contacts, the fingerprint plots and molecular surface contours (dnorm, di and de) provide the information about the percentage contributions [H⋯H (40.5%), C⋯H (29.2%), Cu⋯O (4.7%), N⋯H (4.9%), N⋯O (1.5%) and O⋯H (17.4%)] and revealed them major and minor contributions of the bond interactions for [Cu(5-aip) (3-pic)2]n complex. According to UV–Vis spectrum, d-d transition observed at 712 nm (e = 65 dm3mol−1cm−1) which is assigned to the dz2 (a1)→dx2-y2 (b1) transition. Thermogravimetric analysis was carried out to fallow the thermal stability of the complex." @default.
• W3000412301 created "2020-01-23" @default.
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• W3000412301 date "2020-04-01" @default.
• W3000412301 modified "2023-10-16" @default.
• W3000412301 title "Synthesis, characterization, crystal structure, Hirshfeld surface analysis and spectroscopic properties of bis(5-aminoisophthalato)bispicolinecopper (II)" @default.
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• W3000412301 doi "https://doi.org/10.1016/j.molstruc.2020.127741" @default.
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