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• W3000417964 abstract "Two novel phthalonitrile derivatives, bearing two hexyloxy groups and a benzodioxin (or a naphthodioxin) annulated ring, along with their corresponding metal-free phthalocyanines (H2Pc) were prepared. FT-IR, mass, electronic absorption, 1H NMR, and 13C NMR spectroscopy were employed for the characterization of all compounds. The effect of hexadeca substituents on the photophysical properties of metal-free Pcs was investigated. Photophysical properties of H2Pc were studied in tetrahydrofuran (THF). Fluorescent quantum yields of phthalocyanines (Pcs) were calculated and compared with the unsubstituted phthalocyanine. 1,4-Benzoquinone effectively quenched the fluorescence of these compounds in THF. Cyclic and square wave voltammetry methods were applied to metal-free phthalocyanines and Pc-centered oxidation and reduction processes were obtained." @default.
• W3000417964 created "2020-01-23" @default.
• W3000417964 creator A5075560293 @default.
• W3000417964 creator A5084748999 @default.
• W3000417964 date "2020-01-16" @default.
• W3000417964 modified "2023-10-18" @default.
• W3000417964 title "α- and β-Substituted Metal-Free Phthalocyanines: Synthesis, Photophysical and Electrochemical Properties" @default.
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• W3000417964 doi "https://doi.org/10.3390/molecules25020363" @default.
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