FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3000461106> ?p ?o ?g. }

• W3000461106 endingPage "4245" @default.
• W3000461106 startingPage "4242" @default.
• W3000461106 abstract "Abstract Herein, we present the synthesis of the bench‐stable sodium bicyclo[1.1.1]pentanesulfinate (BCP‐SO 2 Na) and its application in the synthesis of bicyclo[1.1.1]pentyl (BCP) sulfones and sulfonamides. The salt can be obtained in a four‐step procedure from commercially available precursors in multigram scale without the need for column chromatography or crystallization. Sulfinates are known to be useful precursors in radical and nucleophilic reactions and are widely used in medicinal chemistry. This building block enables access to BCP sulfones and sulfonamides avoiding the volatile [1.1.1]propellane which is favorable for the extension of SAR studies. Further, BCP‐SO 2 Na enables the synthesis of products that were not available with previous methods. A chlorination of BCP‐SO 2 Na and subsequent reaction with a Grignard reagent provides a new route to BCP sulfoxides. Several products were analyzed by single‐crystal X‐ray diffraction." @default.
• W3000461106 created "2020-01-23" @default.
• W3000461106 creator A5036763920 @default.
• W3000461106 creator A5043452704 @default.
• W3000461106 creator A5052144587 @default.
• W3000461106 creator A5058807692 @default.
• W3000461106 date "2020-03-03" @default.
• W3000461106 modified "2023-10-17" @default.
• W3000461106 title "Sodium Bicyclo[1.1.1]pentanesulfinate: A Bench‐Stable Precursor for Bicyclo[1.1.1]pentylsulfones and Bicyclo‐ [1.1.1]pentanesulfonamides" @default.
• W3000461106 cites W1999505887 @default.
• W3000461106 cites W2021481369 @default.
• W3000461106 cites W2031190892 @default.
• W3000461106 cites W2041506853 @default.
• W3000461106 cites W2074274985 @default.
• W3000461106 cites W2100446581 @default.
• W3000461106 cites W2129923095 @default.
• W3000461106 cites W2130841503 @default.
• W3000461106 cites W2138628443 @default.
• W3000461106 cites W2155519354 @default.
• W3000461106 cites W2180674417 @default.
• W3000461106 cites W2233221955 @default.
• W3000461106 cites W2267373025 @default.
• W3000461106 cites W2331484215 @default.
• W3000461106 cites W2551943858 @default.
• W3000461106 cites W2558532087 @default.
• W3000461106 cites W2603377947 @default.
• W3000461106 cites W2631713386 @default.
• W3000461106 cites W2744601710 @default.
• W3000461106 cites W2752105738 @default.
• W3000461106 cites W2766712262 @default.
• W3000461106 cites W2772627034 @default.
• W3000461106 cites W2782912308 @default.
• W3000461106 cites W2784913318 @default.
• W3000461106 cites W2804443609 @default.
• W3000461106 cites W2894838047 @default.
• W3000461106 cites W2898834955 @default.
• W3000461106 cites W2900566379 @default.
• W3000461106 cites W2946846376 @default.
• W3000461106 cites W2956147480 @default.
• W3000461106 cites W2966894015 @default.
• W3000461106 cites W2974517436 @default.
• W3000461106 cites W2980229697 @default.
• W3000461106 cites W2984888576 @default.
• W3000461106 cites W2990479146 @default.
• W3000461106 cites W3000461106 @default.
• W3000461106 doi "https://doi.org/10.1002/chem.202000097" @default.
• W3000461106 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7187227" @default.
• W3000461106 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31922305" @default.
• W3000461106 hasPublicationYear "2020" @default.
• W3000461106 type Work @default.
• W3000461106 sameAs 3000461106 @default.
• W3000461106 citedByCount "9" @default.
• W3000461106 countsByYear W30004611062020 @default.
• W3000461106 countsByYear W30004611062021 @default.
• W3000461106 countsByYear W30004611062022 @default.
• W3000461106 countsByYear W30004611062023 @default.
• W3000461106 crossrefType "journal-article" @default.
• W3000461106 hasAuthorship W3000461106A5036763920 @default.
• W3000461106 hasAuthorship W3000461106A5043452704 @default.
• W3000461106 hasAuthorship W3000461106A5052144587 @default.
• W3000461106 hasAuthorship W3000461106A5058807692 @default.
• W3000461106 hasBestOaLocation W30004611061 @default.
• W3000461106 hasConcept C161790260 @default.
• W3000461106 hasConcept C178790620 @default.
• W3000461106 hasConcept C178907741 @default.
• W3000461106 hasConcept C185592680 @default.
• W3000461106 hasConcept C21951064 @default.
• W3000461106 hasConcept C24961977 @default.
• W3000461106 hasConcept C2776371256 @default.
• W3000461106 hasConcept C2779352185 @default.
• W3000461106 hasConcept C40875361 @default.
• W3000461106 hasConcept C537181965 @default.
• W3000461106 hasConceptScore W3000461106C161790260 @default.
• W3000461106 hasConceptScore W3000461106C178790620 @default.
• W3000461106 hasConceptScore W3000461106C178907741 @default.
• W3000461106 hasConceptScore W3000461106C185592680 @default.
• W3000461106 hasConceptScore W3000461106C21951064 @default.
• W3000461106 hasConceptScore W3000461106C24961977 @default.
• W3000461106 hasConceptScore W3000461106C2776371256 @default.
• W3000461106 hasConceptScore W3000461106C2779352185 @default.
• W3000461106 hasConceptScore W3000461106C40875361 @default.
• W3000461106 hasConceptScore W3000461106C537181965 @default.
• W3000461106 hasFunder F4320320879 @default.
• W3000461106 hasIssue "19" @default.
• W3000461106 hasLocation W30004611061 @default.
• W3000461106 hasLocation W30004611062 @default.
• W3000461106 hasLocation W30004611063 @default.
• W3000461106 hasLocation W30004611064 @default.
• W3000461106 hasLocation W30004611065 @default.
• W3000461106 hasLocation W30004611066 @default.
• W3000461106 hasOpenAccess W3000461106 @default.
• W3000461106 hasPrimaryLocation W30004611061 @default.
• W3000461106 hasRelatedWork W1975936676 @default.
• W3000461106 hasRelatedWork W2021939235 @default.
• W3000461106 hasRelatedWork W2322668185 @default.
• W3000461106 hasRelatedWork W2414406995 @default.
• W3000461106 hasRelatedWork W2949780496 @default.
• W3000461106 hasRelatedWork W2950703253 @default.

• next