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• W3000488662 endingPage "106060" @default.
• W3000488662 startingPage "106060" @default.
• W3000488662 abstract "Standard molar enthalpies of vaporization/sublimation of nitro and amino-substituted benzaldehydes were obtained from the temperature dependence of vapour pressure measured by the transpiration method. Enthalpies of fusion of these compounds were measured by using DSC. Solution enthalpies of nitro and amino-substituted benzaldehydes were measured by using a solution calorimeter. Available from literature primary experimental results on temperature dependences of vapour pressures have been collected and they have been treated uniformly in order to derive vaporization/sublimation enthalpies at the reference temperature 298.15 K. Standard molar enthalpies of formation of crystalline isomers of nitro-benzaldehydes were measured by using combustion calorimetry. Gas phase molar enthalpies of formation of substituted benzaldehydes were calculated by the high-level quantum-chemical G4 method and they were used for evaluation of available experimental results. A set of thermodynamic properties of substituted benzaldehydes was recommended as reliable reference properties for thermochemical calculations. Simple group-additivity procedures were developed for estimation of vaporization enthalpies, gas-phase, and liquid-phase enthalpies of formation of substituted benzenes." @default.
• W3000488662 created "2020-01-23" @default.
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• W3000488662 date "2020-04-01" @default.
• W3000488662 modified "2023-10-18" @default.
• W3000488662 title "Thermochemistry of di-substituted benzenes: nitro- and dimethylamino benzaldehydes" @default.
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• W3000488662 doi "https://doi.org/10.1016/j.jct.2020.106060" @default.
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