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• W3000615061 abstract "To explore an efficient photocatalyst for NO pollution, a direct Z-scheme photocatalytic system is successfully fabricated by coupling Bi2WO6 with NH2-UiO-66 via a simple hydrothermal synthesis technique. The Z-scheme system promotes the NO photocatalytic oxidation activity with an optimum NO removal rate of 79%, which is 2.7 and 1.2 times that obtained by using only pristine Bi2WO6 and NH2-UiO-66, respectively. Simultaneously, superior selectivity for converting NO to NO3-/NO2- is observed. The enhanced photocatalytic performance of the Bi2WO6/NH2-UiO-66 hybrids is attributed to the following two aspects: (i) large specific area of NH2-UiO-66, which exposes more active sites and is beneficial to the adsorption and activation of NO; (ii) outstanding Z-scheme structure constructed between BiWO6 and NH2-UiO-66, which can improve the efficiency of the separation of electron-hole pairs and preserves the strong oxidation ability of hybrids. ESR analysis shows that ·O2- and ·OH contribute to NO removal. A possible photocatalytic mechanism of NO oxidation on the direct Z-scheme photocatalyst (BWO/2NU) under visible light irradiation is proposed. This work displays the BWO/2NU hybrid's potential for treating low-concentration air pollutants, and the proposed Z-scheme photocatalyst design and promotion mechanism may inspire more rational synthesis of highly efficient photocatalysts for NO removal." @default.
• W3000615061 created "2020-01-23" @default.
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• W3000615061 date "2020-01-01" @default.
• W3000615061 modified "2023-10-13" @default.
• W3000615061 title "A direct <i>Z</i>-scheme Bi₂WO₆/NH₂-UiO-66 nanocomposite as an efficient visible-light-driven photocatalyst for NO removal" @default.
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• W3000615061 doi "https://doi.org/10.1039/c9ra09270f" @default.
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