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- W3000641036 abstract "Abstract A series of chloroalkynes activated with extremely strong electron withdrawing polyfluoroalkyloxalyl substituents were prepared for the first time from available bis(trimethylstannyl) acetylene and the corresponding acid chlorides. Hexafluoroisopropyl ester, thus obtained, probably proved to be the most electrophilic alkyne known so far. It is not only extremely strong dienophile in the Diels-Alder reaction, but undergoes the unusual uncatalyzed [2+2]-cycloaddition reactions with simple alkenes under very mild conditions." @default.
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- W3000641036 date "2020-03-01" @default.
- W3000641036 modified "2023-10-17" @default.
- W3000641036 title "Polyfluorinated esters of 4-chloro-2-oxobut-3-ynoic acid. Cycloaddition reactons of hexafluoroisopropyl 4-chloro-2-oxobut-3-ynoate, an incredibly electrophilic alkyne" @default.
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- W3000641036 doi "https://doi.org/10.1016/j.jfluchem.2020.109463" @default.
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