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• W3000762561 abstract "Abstract The P4VP with the molecular weight of 12 K and the molecular weight distribution of 1.2 was synthesized via reversible addition‐fragmentation chain transfer polymerization. Then it was added to the system for the preparation of ZIF‐8 as a surfactant. A special two‐dimensional (2D) sheet was produced because P4VP could promote the lateral growth of ZIF‐8. Additionally, the pyridine group from P4VP chains could complex Au 3+ followed by in‐situ reduction under UV light to form the 2D ZIF‐8/P4VP/Au ternary hybrids. The ternary layered ZIF‐8/P4VP/Au hybrids exhibited a good yield for epoxy carbonate of 71 % and the high time‐space yield of 3.22 h −1 in the reaction of carbon dioxide with propylene oxide, which was much higher than 0.425 h −1 of the conventional homogeneous catalyst KI. Besides, the ternary layered ZIF‐8/P4VP/Au showed good stability, the catalytic performance was unchanged after three cycles." @default.
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• W3000762561 date "2020-01-20" @default.
• W3000762561 modified "2023-09-28" @default.
• W3000762561 title "Highly Efficient Catalysts for Conversion of CO ₂ into Cyclic Carbonates Based on the Ternary Layered ZIF‐8/P4VP/Au Hybrids" @default.
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• W3000762561 doi "https://doi.org/10.1002/slct.201904690" @default.
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