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- W3000767851 abstract "Fluorination of C₆₀ at 550°C leads to milligram quantities of two stable fullerene derivatives with 58-carbon cage structures: C₅₈F₁₈ and C₅₈F₁₇CF₃. The compounds were characterized by mass spectrometry and fluorine nuclear magnetic resonance spectroscopy, and the data support a heptagonal ring in the framework. The resulting strain, which has hindered past attempts to prepare these smaller quasi-fullerenes, is mitigated here by hybridization change of some of the carbons in the pentagons from sp² to sp³ because of fluorine addition. The loss of carbon from C₆₀ is believed to occur via sequential fluorine addition to a C-C single bond and an adjacent C{dbond}C bond, followed by loss of a :CF₂ carbene." @default.
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- W3000767851 date "2005-01-01" @default.
- W3000767851 modified "2023-10-06" @default.
- W3000767851 title "Isolation of Two Seven-Membered Ring C₅₈ Fullerene Derivatives: C₅₈F₁₇CF₃ and C₅₈F₁₈" @default.
- W3000767851 hasPublicationYear "2005" @default.
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