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- W3000799518 abstract "New solid solutions, LixY(VO4)1-xF4x (0 < x ≤ 0.1), were successfully prepared via solid state reaction method by combination of orthovanadate YVO4 (Zircon structure) and LiYF4 fluoride (Scheelite structure). The structures were determined by X-ray diffraction and profil-matching refinements. Solid state nuclear magnetic resonance, Fourier transforms infrared and Raman spectroscopies with scanning electron microscopy were used to describe the microstructure and chemical composition of the as-prepared ceramics. It was found that solid solutions in the range 0 < x ≤ 0.1 are structurally similar to the zircon structure of YVO4. The luminescence properties of Eu3+ doped samples were investigated. Under excitation of 398 nm, the LixY1-yEuy(VO4)1-xF4x (x = 0.05, 0.07, 0.1; y = 0.05, 0.10, 0.15, 0.20) solid solution exhibited red emission originating from the strongest 5D0→7F2 transition. As the amount of Li+ and F− contents increases, the photoluminescence efficiency improved. So, the solid solution ceramics can be considered promising red phosphors for light-emitting diodes." @default.
- W3000799518 created "2020-01-30" @default.
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- W3000799518 date "2020-04-01" @default.
- W3000799518 modified "2023-10-18" @default.
- W3000799518 title "New solid solution ceramics LixY1-yEuy(VO4)1-xF4x (0 <x≤ 0.1; 0 <y≤ 0.2): Synthesis, structural characterization and luminescence properties" @default.
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- W3000799518 doi "https://doi.org/10.1016/j.jssc.2020.121223" @default.
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