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- W3000851808 abstract "Abstract Wetting of noble metals on oxide structures becomes problematic when attempting to grow two-dimensional, atomically smooth and continuous thin film structures because of a strong tendency for three-dimensional growth. This study redefines the crucial factor that controls the wetting of vacuum deposited Ag on SiO2 substrates and refutes the currently accepted assertion that increasing the nucleation density of Ag is responsible for promoting wetting. Ultrahigh-resolution electron microscopy, supported by X-ray spectroscopic techniques, was used to observe how fast Ag nanoparticles evolve to a continuous film by manipulating the contribution of the crucial factor on Ag wetting, and the results were numerically interpreted using first-principles density functional theory calculations to reveal the relevant dynamics. The experimental and numerical results confirmed that the earliest transition of the coalescence dynamics of Ag nanoparticles from full to partial coalescence is the dominating factor in improving Ag wetting. Surprisingly, Ag wetting is independent of the initial nucleation density of Ag nanoparticles. Favorable partial coalescence with more irregularities in the shapes was readily attainable by artificially reducing the thermodynamic surface and interfacial free energies of the evolving Ag nanoparticles through the addition of a small concentration of Al or O as a wetting agent." @default.
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- W3000851808 date "2020-04-01" @default.
- W3000851808 modified "2023-10-17" @default.
- W3000851808 title "Strategy for improving Ag wetting on oxides: Coalescence dynamics versus nucleation density" @default.
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- W3000851808 doi "https://doi.org/10.1016/j.apsusc.2020.145515" @default.
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