Matches in SemOpenAlex for { <https://semopenalex.org/work/W3000990590> ?p ?o ?g. }
- W3000990590 endingPage "3537" @default.
- W3000990590 startingPage "3527" @default.
- W3000990590 abstract "Carbon monoxide is a naturally occurring gasotransmitter combining inherent toxicity with a remarkable therapeutic potential and arduous administration. Photoactivatable carbon monoxide-releasing molecules (photoCORMs) are chemical agents that allow for precise spatial and temporal control over the CO release. In this work, we present a comprehensive mechanistic study of the photochemical CO release from 3-hydroxy-2-phenyl-4H-chromen-4-one, a π-extended 3-hydroxyflavone photoCORM, in methanol using steady-state and transient absorption spectroscopies and quantum chemical calculations. The multiplicity of the productive excited states and the role of oxygen (O2) in the CO production are emphasized, revealing a photoreaction dichotomy of the 3-hydroxyflavone acid and base forms. The utilization of three major orthogonal mechanistic pathways, all of which lead to the CO release, can fuel future endeavors to improve the CO release efficacy of 3-hydroxyflavone-based derivatives and refine their potential medical applications as photoCORMs." @default.
- W3000990590 created "2020-01-30" @default.
- W3000990590 creator A5030406175 @default.
- W3000990590 creator A5031400447 @default.
- W3000990590 creator A5046701485 @default.
- W3000990590 creator A5087706538 @default.
- W3000990590 date "2020-01-24" @default.
- W3000990590 modified "2023-10-10" @default.
- W3000990590 title "Mechanisms of Orthogonal Photodecarbonylation Reactions of 3-Hydroxyflavone-Based Acid–Base Forms" @default.
- W3000990590 cites W1495383632 @default.
- W3000990590 cites W1512336465 @default.
- W3000990590 cites W1534309105 @default.
- W3000990590 cites W1565619320 @default.
- W3000990590 cites W1839264092 @default.
- W3000990590 cites W1969249329 @default.
- W3000990590 cites W1975867105 @default.
- W3000990590 cites W1978629989 @default.
- W3000990590 cites W1979092385 @default.
- W3000990590 cites W1981257884 @default.
- W3000990590 cites W1990039009 @default.
- W3000990590 cites W1993214957 @default.
- W3000990590 cites W1993323069 @default.
- W3000990590 cites W1995935632 @default.
- W3000990590 cites W1997151511 @default.
- W3000990590 cites W1998754668 @default.
- W3000990590 cites W2000268335 @default.
- W3000990590 cites W2000571085 @default.
- W3000990590 cites W2003677736 @default.
- W3000990590 cites W2007636933 @default.
- W3000990590 cites W2012117939 @default.
- W3000990590 cites W2013030616 @default.
- W3000990590 cites W2017303728 @default.
- W3000990590 cites W2030467206 @default.
- W3000990590 cites W2031760076 @default.
- W3000990590 cites W2046260237 @default.
- W3000990590 cites W2049509227 @default.
- W3000990590 cites W2058210956 @default.
- W3000990590 cites W2065233162 @default.
- W3000990590 cites W2066053481 @default.
- W3000990590 cites W2067468176 @default.
- W3000990590 cites W2077580537 @default.
- W3000990590 cites W2078146328 @default.
- W3000990590 cites W2078408605 @default.
- W3000990590 cites W2081546649 @default.
- W3000990590 cites W2081907389 @default.
- W3000990590 cites W2109207908 @default.
- W3000990590 cites W2130699930 @default.
- W3000990590 cites W2134404850 @default.
- W3000990590 cites W2137932077 @default.
- W3000990590 cites W2143861549 @default.
- W3000990590 cites W2143981217 @default.
- W3000990590 cites W2148284063 @default.
- W3000990590 cites W2165643909 @default.
- W3000990590 cites W2165989556 @default.
- W3000990590 cites W2169891574 @default.
- W3000990590 cites W2171108386 @default.
- W3000990590 cites W2264956482 @default.
- W3000990590 cites W2289244293 @default.
- W3000990590 cites W2312848220 @default.
- W3000990590 cites W2318301258 @default.
- W3000990590 cites W2324849564 @default.
- W3000990590 cites W2326679706 @default.
- W3000990590 cites W2403521488 @default.
- W3000990590 cites W2408721512 @default.
- W3000990590 cites W2493041787 @default.
- W3000990590 cites W2510261040 @default.
- W3000990590 cites W2519214930 @default.
- W3000990590 cites W2587833196 @default.
- W3000990590 cites W2590433918 @default.
- W3000990590 cites W2605593378 @default.
- W3000990590 cites W2638716394 @default.
- W3000990590 cites W2728149188 @default.
- W3000990590 cites W2778988344 @default.
- W3000990590 cites W2792601795 @default.
- W3000990590 cites W2810728092 @default.
- W3000990590 cites W2858137067 @default.
- W3000990590 cites W2910215830 @default.
- W3000990590 cites W2951123545 @default.
- W3000990590 cites W4319308571 @default.
- W3000990590 doi "https://doi.org/10.1021/acs.joc.9b03248" @default.
- W3000990590 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31977220" @default.
- W3000990590 hasPublicationYear "2020" @default.
- W3000990590 type Work @default.
- W3000990590 sameAs 3000990590 @default.
- W3000990590 citedByCount "22" @default.
- W3000990590 countsByYear W30009905902020 @default.
- W3000990590 countsByYear W30009905902021 @default.
- W3000990590 countsByYear W30009905902022 @default.
- W3000990590 countsByYear W30009905902023 @default.
- W3000990590 crossrefType "journal-article" @default.
- W3000990590 hasAuthorship W3000990590A5030406175 @default.
- W3000990590 hasAuthorship W3000990590A5031400447 @default.
- W3000990590 hasAuthorship W3000990590A5046701485 @default.
- W3000990590 hasAuthorship W3000990590A5087706538 @default.
- W3000990590 hasConcept C147597530 @default.
- W3000990590 hasConcept C161790260 @default.
- W3000990590 hasConcept C178790620 @default.
- W3000990590 hasConcept C185592680 @default.