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- W3001087384 abstract "Herein, we report the stereoselective synthesis of (1 + n)-membered cycloalkane from methyl ketone and 1,n-diol. A manganese(I) complex bearing a phosphine-free ligand catalyzed the reaction, which involved the formation of two C–C bonds via a sequence of intermolecular- and intramolecular-borrowing hydrogenation reactions. It produces 2 mol of water as the sole byproduct, making the process atom economical and environmentally benign. Multisubstituted cycloalkanes were obtained in good to excellent yields with very high selectivities. A thorough mechanistic analysis by high-level DFT computation rationalizes the choice of the pincer and establishes the role of hemilability of the ligand for this efficient transformation." @default.
- W3001087384 created "2020-01-30" @default.
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- W3001087384 date "2020-01-24" @default.
- W3001087384 modified "2023-10-14" @default.
- W3001087384 title "A Phosphine-Free Manganese Catalyst Enables Stereoselective Synthesis of (1 + <i>n</i>)-Membered Cycloalkanes from Methyl Ketones and 1,<i>n</i>-Diols" @default.
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- W3001087384 doi "https://doi.org/10.1021/acscatal.9b05567" @default.
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