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- W3001241569 endingPage "122143" @default.
- W3001241569 startingPage "122143" @default.
- W3001241569 abstract "Haloacetic acids (HAAs) are a group of pollutants ubiquitous in natural environment and anthropogenic systems, and therefore in need of control. Photolysis and photocatalysis techniques via ultraviolet (UV)-based technologies have held promise for decades in degrading organic molecules in water, but their capacities in removing HAAs remain to be explored. To better understand the trends in the existing literature and to identify the knowledge gaps that may merit further exploration, this review compares the HAAs photodegradation kinetics, influencing factors, reaction products, pathways, and mechanisms for a variety of UV technologies. The selected UV processes are classified into three types: UV-only photolysis, photooxidation, and photoreduction. Overall, although trends vary significantly depending upon many factors, the photo-susceptibility of HAAs always increases with rising molecular weight of substituted halogen atom(s), with those chlorinated HAAs being the most refractory species. Notably, while many processes proved hydroxyl radical (OH) as the forcing driver, the patterns of kinetics among HAAs were not consistent among processes, suggesting that OH was not the only driver. Compared to earlier studies focusing on specific technologies to treat numerous contaminants through a material perspective, this review commits to understanding the commonalities and differences among multiple UV-based technologies in treating only one group of compound mainly via a chemistry viewpoint." @default.
- W3001241569 created "2020-01-30" @default.
- W3001241569 creator A5004375357 @default.
- W3001241569 creator A5015997243 @default.
- W3001241569 creator A5033652627 @default.
- W3001241569 creator A5055149893 @default.
- W3001241569 creator A5055752694 @default.
- W3001241569 creator A5063800558 @default.
- W3001241569 creator A5064018447 @default.
- W3001241569 date "2020-06-01" @default.
- W3001241569 modified "2023-10-17" @default.
- W3001241569 title "Photolysis and photocatalysis of haloacetic acids in water: A review of kinetics, influencing factors, products, pathways, and mechanisms" @default.
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