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- W3001330479 abstract "Think of bismuth as the Cinderella of the periodic table. Because it is surrounded by its toxic stepsiblings—the elements lead, tin, antimony, tellurium, and polonium—chemists often overlook bismuth as a possible reagent. But bismuth and its compounds are safe enough to use in pharmaceuticals, in cosmetics, and as a replacement for lead materials in plumbing systems. Now, chemists at the Max Planck Institute for Kohlenforschung are giving bismuth a chance to shine, plucking it from the periodic table and fashioning it into a redox complex that mimics the actions of a transition-metal catalytic cycle. “Our idea was: If transition metals have been so successful following certain rules, can we basically take bismuth and make it behave like a transition metal?” explains Josep Cornella, who led the research project. But bismuth has some peculiar properties. It can coordinate up to nine ligands and adopt geometries that differ from those of transition" @default.
- W3001330479 created "2020-01-30" @default.
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- W3001330479 date "2020-01-20" @default.
- W3001330479 modified "2023-10-16" @default.
- W3001330479 title "Bismuth’s big break" @default.
- W3001330479 doi "https://doi.org/10.1021/cen-09803-scicon6" @default.
- W3001330479 hasPublicationYear "2020" @default.
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