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• W3001955418 abstract "The chemical synthesis of C60 fullerene in the laboratory is still a challenge. In order to achieve this goal, we propose a synthetic route based on the dimerization between two pentacyclopentacorannulene (C30H10) fragments employing the Diels-Alder cycloaddition reaction. Density functional calculations indicate that a step wise non-concerted dimerization mechanism of C30H10 is favored over a one stage dimerization. The step wise dimerization implies the sequential formation of 2, 4, 6, and 10 new C-C bonds between the two fragments. This leads to the formation of the Diels-Alder cycloadduct C60H20. The results then suggest the synthesis of C60H20 as a precursor for C60. The synthesis of the analogue C60F20 has already been reported." @default.
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• W3001955418 date "2020-01-01" @default.
• W3001955418 modified "2023-10-12" @default.
• W3001955418 title "Dimerization of pentacyclopentacorannulene C₃₀H₁₀ as a strategy to produce C₆₀H₂₀ as a precursor for C₆₀" @default.
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• W3001955418 doi "https://doi.org/10.1039/c9ra09804f" @default.
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