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- W3002111993 abstract "A simple solvent- and catalyst-free method is presented for the synthesis of the large-pore metal–organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, crystalline films of a large-pore material could be deposited for the first time entirely from the vapor phase. A combination of positron annihilation lifetime spectroscopy (PALS) and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diameter ∼2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), pair distribution function (PDF), and extended X-ray absorption fine structure (EXAFS). The exceptional uptake capacity of MAF-6 in comparison to ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows." @default.
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- W3002111993 date "2020-01-22" @default.
- W3002111993 modified "2023-10-16" @default.
- W3002111993 title "Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Large-Pore Metal–Organic Framework MAF-6" @default.
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- W3002111993 doi "https://doi.org/10.1021/acs.chemmater.9b03807" @default.
- W3002111993 hasPublicationYear "2020" @default.
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