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- W3002197873 endingPage "118086" @default.
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- W3002197873 abstract "Excited-state intramolecular proton transfer (ESIPT) and twist intramolecular charge transfer (TICT) are the two most fundamental dynamic processes, ubiquitous in biological and chemical reactions. The excited-state properties of (E-8-((4-dimethylamino-phenylimino)-methyl)-7-hydroxy-4-methyl-2H-chromen-2-one (CDPA) in various solvents with different polarities were investigated by using steady-state and femtosecond transient absorption spectroscopy combined with DFT/TDDFT calculations. The results demonstrated that CDPA exhibited low fluorescence in polar acetonitrile (ACN) due to ESIPT but high fluorescence in nonpolar n-Hexane was attributed to intramolecular rotation blocking ESIPT. TDDFT calculations confirmed that the dramatic phenyl group torsional of CDPA in Hexane, whereas a near planar conformation in ACN solvent. The ESIPT barrier decreases regularly with the increase of solvent polarity from n-Hexane, tetrahydrofuran to ACN solvent. These results demonstrated that the ESIPT and TICT processes of CDPA are competitive mechanisms. Our work revealed the effect solvent polarity on the emission behavior and excited-state deactivation mechanism of CDPA, which could help to design and develop new polarity probe in the microenvironments." @default.
- W3002197873 created "2020-01-30" @default.
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- W3002197873 date "2020-04-01" @default.
- W3002197873 modified "2023-10-12" @default.
- W3002197873 title "The role played by solvent polarity in regulating the competitive mechanism between ESIPT and TICT of coumarin (E-8-((4-dimethylamino-phenylimino)-methyl)-7-hydroxy-4-methyl-2H-chromen-2-one)" @default.
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- W3002197873 doi "https://doi.org/10.1016/j.saa.2020.118086" @default.
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