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- W3002262009 abstract "Abstract [SnI 8 {Fe(CO) 4 } 4 ][Al 2 Cl 7 ] 2 enthält ein [SnI 8 {Fe(CO) 4 } 4 ] 2+ ‐Kation mit einem beispiellos hochkoordinierten, zweifach überdachten SnI 8 ‐Prisma. In Anbetracht der achtfachen Koordination mit dem voluminösesten, stabilen Halogenid ist es umso erstaunlicher, dass die SnI 8 ‐Baugruppe nur von fragilen Fe(CO) 4 ‐Gruppen klammerartig umgeben ist. Trotz der überwiegend ionischen Bindungssituation in [SnI 8 {Fe(CO) 4 } 4 ] 2+ sind die I − ⋅⋅⋅I − ‐Abstände verkleinert (bis zu 371 pm) und liegen deutlich unter dem Van‐der‐Waals‐Abstand (420 pm). Charakterisiert wurde die Titelverbindung durch Einkristallstrukturanalyse, spektroskopische Methoden (EDXS, FT‐IR, Raman, UV/Vis, Mößbauer), Thermogravimetrie und Dichtefunktionaltheorie." @default.
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- W3002262009 date "2020-01-23" @default.
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- W3002262009 title "[SnI<sub>8</sub>{Fe(CO)<sub>4</sub>}<sub>4</sub>]<sup>2+</sup>: eine hochkoordinierte Sn<sup>+II</sup>I<sub>8</sub>‐Baueinheit mit fragilen Carbonylklammern" @default.
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- W3002262009 doi "https://doi.org/10.1002/ange.201911126" @default.
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