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• W3002300900 endingPage "261" @default.
• W3002300900 startingPage "261" @default.
• W3002300900 abstract "The intumescent process of sodium (substituted) phenolates has been studied. The generation of hydrogen radical via a homolytic cleavage of the Ar–H bond and the subsequent hydroarylation of phenolates to cyclohexadienes along with cyclization and elimination reactions of cyclohexadienes are critical steps in the base promoted intumescence of phenols. The substituents show great influence on the intumescence of phenolates. Phenolates substituted with a weak electron donating group enable intumescence while those with an electron withdrawing group or strong electron donating group suppresses intumescence. This distinction can be justified by both electronic and steric effects of substituents on the generation of hydrogen radical and the degree of hydroarylation." @default.
• W3002300900 created "2020-01-30" @default.
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• W3002300900 date "2020-01-23" @default.
• W3002300900 modified "2023-10-16" @default.
• W3002300900 title "Base Promoted Intumescence of Phenols" @default.
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• W3002300900 doi "https://doi.org/10.3390/polym12020261" @default.
• W3002300900 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7077410" @default.
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