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• W3002471142 endingPage "3286" @default.
• W3002471142 startingPage "3277" @default.
• W3002471142 abstract "The promotion of mixed-valence interactions between redox-active, π-conjugated scaffolds is of interest when developing new conducting or electrochromic materials as well as in the construction of redox-controlled supramolecular assemblies. In this work, dimeric structures of the redox-active indenofluorene-extended tetrathiafulvalene (IF-TTF) unit were synthesized in a stepwise protocol. The synthesis relied on the development of a new unsymmetrical IF-TTF building block by a combination of phosphite-mediated and Horner–Wadsworth–Emmons reactions for introduction of the dithiafulvene units. The redox properties were studied by cyclic voltammetry, where it was observed that a first one-electron oxidation, corresponding to a mixed-valence state, occurs at a significantly lower potential when the IF-TTF unit is incorporated into a dimer, compared to a monomer analogue. This result indicates that locking the redox-active IF-TTF units in close proximity promotes intramolecular mixed-valence interactions. A computational study was also conducted, supporting the involvement of intramolecular interactions." @default.
• W3002471142 created "2020-01-30" @default.
• W3002471142 creator A5038586300 @default.
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• W3002471142 date "2020-01-27" @default.
• W3002471142 modified "2023-09-24" @default.
• W3002471142 title "Toward Redox-Active Indenofluorene-Extended Tetrathiafulvalene Oligomers—Synthesis and Studies of Dimeric Scaffolds" @default.
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• W3002471142 doi "https://doi.org/10.1021/acs.joc.9b03118" @default.
• W3002471142 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31984743" @default.
• W3002471142 hasPublicationYear "2020" @default.
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