Matches in SemOpenAlex for { <https://semopenalex.org/work/W3002909232> ?p ?o ?g. }
- W3002909232 endingPage "2816" @default.
- W3002909232 startingPage "2806" @default.
- W3002909232 abstract "Solid-state electrolytes are crucial for the realization of safe and high capacity all-solid-state batteries. Lithium-containing complex hydrides represent a promising class of solid-state electrolytes, but they exhibit low ionic conductivities at room temperature. Ion substitution and nanoconfinement are the main strategies to overcome this challenge. Here, we report on the synthesis of nanoconfined anion-substituted complex hydrides in which the two strategies are effectively combined to achieve a profound increase in the ionic conductivities at ambient temperature. We show that the nanoconfinement of anion substituted LiBH4 (LiBH4–LiI and LiBH4–LiNH2) leads to an enhancement of the room temperature conductivity by a factor of 4 to 10 compared to nanoconfined LiBH4 and nonconfined LiBH4–LiI and LiBH4-LiNH2, concomitant with a lowered activation energy of 0.44 eV for Li-ion transport. Our work demonstrates that a combination of partial ion substitution and nanoconfinement is an effective strategy to boost the ionic conductivity of complex hydrides. The strategy could be applicable to other classes of solid-state electrolytes." @default.
- W3002909232 created "2020-01-30" @default.
- W3002909232 creator A5000028722 @default.
- W3002909232 creator A5018736655 @default.
- W3002909232 creator A5024063649 @default.
- W3002909232 creator A5040096948 @default.
- W3002909232 creator A5065689668 @default.
- W3002909232 creator A5085418285 @default.
- W3002909232 date "2020-01-21" @default.
- W3002909232 modified "2023-10-16" @default.
- W3002909232 title "Combined Effects of Anion Substitution and Nanoconfinement on the Ionic Conductivity of Li-Based Complex Hydrides" @default.
- W3002909232 cites W1572819095 @default.
- W3002909232 cites W1688397566 @default.
- W3002909232 cites W1965298793 @default.
- W3002909232 cites W1971958580 @default.
- W3002909232 cites W1974582866 @default.
- W3002909232 cites W1975883279 @default.
- W3002909232 cites W1978003827 @default.
- W3002909232 cites W1981049412 @default.
- W3002909232 cites W1995041236 @default.
- W3002909232 cites W2002765673 @default.
- W3002909232 cites W2003191941 @default.
- W3002909232 cites W2004237001 @default.
- W3002909232 cites W2004539713 @default.
- W3002909232 cites W2007656979 @default.
- W3002909232 cites W2010434523 @default.
- W3002909232 cites W2012284610 @default.
- W3002909232 cites W2013572715 @default.
- W3002909232 cites W2017510110 @default.
- W3002909232 cites W2022083084 @default.
- W3002909232 cites W2026313916 @default.
- W3002909232 cites W2027815635 @default.
- W3002909232 cites W2028115260 @default.
- W3002909232 cites W2030899889 @default.
- W3002909232 cites W2034647391 @default.
- W3002909232 cites W2042391643 @default.
- W3002909232 cites W2044416616 @default.
- W3002909232 cites W2045674746 @default.
- W3002909232 cites W2046120957 @default.
- W3002909232 cites W2051352594 @default.
- W3002909232 cites W2053554139 @default.
- W3002909232 cites W2064411034 @default.
- W3002909232 cites W2065213773 @default.
- W3002909232 cites W2065234708 @default.
- W3002909232 cites W2065894302 @default.
- W3002909232 cites W2071583984 @default.
- W3002909232 cites W2076993873 @default.
- W3002909232 cites W2085464244 @default.
- W3002909232 cites W2086933486 @default.
- W3002909232 cites W2096735236 @default.
- W3002909232 cites W2100185609 @default.
- W3002909232 cites W2108248445 @default.
- W3002909232 cites W2126180669 @default.
- W3002909232 cites W2134296735 @default.
- W3002909232 cites W2137738759 @default.
- W3002909232 cites W2138520791 @default.
- W3002909232 cites W2141902202 @default.
- W3002909232 cites W2152048732 @default.
- W3002909232 cites W2161826745 @default.
- W3002909232 cites W2294011242 @default.
- W3002909232 cites W2322664963 @default.
- W3002909232 cites W2330498277 @default.
- W3002909232 cites W2472772094 @default.
- W3002909232 cites W2502262097 @default.
- W3002909232 cites W2502810659 @default.
- W3002909232 cites W2518099942 @default.
- W3002909232 cites W2519691757 @default.
- W3002909232 cites W2523882691 @default.
- W3002909232 cites W2576935437 @default.
- W3002909232 cites W2583015190 @default.
- W3002909232 cites W2585989042 @default.
- W3002909232 cites W2587767928 @default.
- W3002909232 cites W2592649293 @default.
- W3002909232 cites W2623355280 @default.
- W3002909232 cites W2761704879 @default.
- W3002909232 cites W2765915055 @default.
- W3002909232 cites W2768039800 @default.
- W3002909232 cites W2769078008 @default.
- W3002909232 cites W2797172904 @default.
- W3002909232 cites W2808374660 @default.
- W3002909232 cites W2808946853 @default.
- W3002909232 cites W2918742558 @default.
- W3002909232 cites W2969829574 @default.
- W3002909232 cites W2189829265 @default.
- W3002909232 doi "https://doi.org/10.1021/acs.jpcc.9b10607" @default.
- W3002909232 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7011749" @default.
- W3002909232 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32064019" @default.
- W3002909232 hasPublicationYear "2020" @default.
- W3002909232 type Work @default.
- W3002909232 sameAs 3002909232 @default.
- W3002909232 citedByCount "32" @default.
- W3002909232 countsByYear W30029092322020 @default.
- W3002909232 countsByYear W30029092322021 @default.
- W3002909232 countsByYear W30029092322022 @default.
- W3002909232 countsByYear W30029092322023 @default.
- W3002909232 crossrefType "journal-article" @default.
- W3002909232 hasAuthorship W3002909232A5000028722 @default.
- W3002909232 hasAuthorship W3002909232A5018736655 @default.