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- W3002923742 abstract "Abstract A molecular adlayer of biphenyl was vapor deposited amorphously onto a single crystal of cryogenically cooled Al2O3. The biphenyl conformer at deposition was determined to be non-planar with a fluorescence λmax ~320 nm. At 161 K biphenyl underwent a disorder-to-order transition which was a planar conformation analogous to the solid crystal with a fluorescence λmax ~345 nm and characterized by a lower fluorescence intensity due to energy transfer. To demonstrate homoepitaxy, a molecular adlayer of biphenyl was vapor deposited and annealed above the disorder-to-order transition temperature. The thinnest adlayer for epitaxial ordering was 35 ML, monolayers, and epitaxy was achieved up to 5000 ML. Heteroepitaxy was demonstrated with p-xylene substrate with biphenyl overlayer. In addition the passage of the xylene through the biphenyl overlayer increased the density of crystalline defect sites and resulted in enhanced fluorescence intensity." @default.
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- W3002923742 date "2020-03-01" @default.
- W3002923742 modified "2023-10-14" @default.
- W3002923742 title "Epitaxial ordering of biphenyl on aromatic hydrocarbon substrates" @default.
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- W3002923742 doi "https://doi.org/10.1016/j.tsf.2020.137823" @default.
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