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- W3003100634 abstract "Abstract Diradicals have been of tremendous interest for over a century ever since the first reports of p ‐ and m ‐phenylene‐bridged diphenylmethylradicals in 1904 by Thiele and 1915 by Schlenk. Reported here are the first examples of cyclic(alkyl)(amino)carbene (CAAC) analogues of Thiele's hydrocarbon, a Kekulé diradical, and Schlenk's hydrocarbon, a non‐Kekulé diradical, without using CAAC as a precursor. The CAAC analogue of Thiele's hydrocarbon has a singlet ground state, whereas the CAAC analogue of Schlenk's hydrocarbon contains two unpaired electrons. The latter forms a dimer, by an intermolecular double head‐to‐tail dimerization. This straightforward synthetic methodology is modular and can be extended for the generation of redox‐active organic compounds." @default.
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- W3003100634 date "2020-03-06" @default.
- W3003100634 modified "2023-10-06" @default.
- W3003100634 title "CAAC‐Based Thiele and Schlenk Hydrocarbons" @default.
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- W3003100634 doi "https://doi.org/10.1002/ange.201915802" @default.
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