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- W3003300029 endingPage "1379" @default.
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- W3003300029 abstract "The synthesis of indanone derivatives by the Rh(III)-catalyzed reaction of α-carbonyl sulfoxonium ylides with activated alkenes is reported. The reaction shows a high tolerance for functional groups and furnishes a variety of substituted indanone derivatives via a formal [4 + 1] cycloaddition. Highly stable sulfoxonium ylides were used as substrates in this C–H functionalization, and their bifunctional character could be effectively exploited using Rh(III) catalysis via sequential double C–C bond formation. Based on mechanistic studies including deuterium-labeling experiments, the reaction is proposed to proceed as follows: Rh(III)-catalyzed C–H oxidative alkenylation via β-hydride elimination, readdition of H–Rh species, a 1,2-carbon shift with the elimination of DMSO, and protonation." @default.
- W3003300029 created "2020-02-07" @default.
- W3003300029 creator A5023225667 @default.
- W3003300029 creator A5074754276 @default.
- W3003300029 creator A5085388925 @default.
- W3003300029 date "2020-02-03" @default.
- W3003300029 modified "2023-09-25" @default.
- W3003300029 title "Rh(III)-Catalyzed Reaction of α-Carbonyl Sulfoxonium Ylides and Alkenes: Synthesis of Indanones via [4 + 1] Cycloaddition" @default.
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- W3003300029 doi "https://doi.org/10.1021/acs.orglett.9b04664" @default.
- W3003300029 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32009402" @default.
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