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- W3003313136 abstract "In this contribution, a one-pot method possessing the advantages of easy preparation, rapidness, efficiency and environmental friendliness has been developed for the first time for the facile synthesis of highly fluorescent actinian nickel-doped carbon nanoflowers (Ni-CNFWs) by using nickel(ii)acetylacetonate as a metal-carbon source. Various characterization studies indicate that metal nickel atoms have been successfully doped into carbon nanoflower frameworks with a weight percentage of 1.46 wt%. The Ni-CNFWs showed a shell-core actinian structure with ∼400 nm diameter and highly efficient fluorescence quenching ability in the presence of quercetin (Qut) due to the formed Meisenheimer complexes via the conjugation effect of p, π-electrons between Ni-CNFWs and Qut, which allowed the analysis of Qut in a very facile method. Under the optimal conditions, the decreased fluorescence of Ni-CNFWs showed a good linear relationship with the concentration of Qut ranging from 0.5 to 300.0 μM, and the limit of detection was 0.137 μM (3σ/k). Finally, the content of Qut in bovine serum was successfully detected with the novel on-off sensor, and the recoveries were 97.3-101.9%, which indicate that the constructed on-off sensor has a high selectivity and accuracy." @default.
- W3003313136 created "2020-02-07" @default.
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- W3003313136 date "2019-01-01" @default.
- W3003313136 modified "2023-10-17" @default.
- W3003313136 title "One-pot green and simple synthesis of actinian nickel-doped carbon nanoflowers for ultrasensitive sensing of quercetin" @default.
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- W3003313136 doi "https://doi.org/10.1039/c9an01907c" @default.
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