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- W3003325360 endingPage "1265" @default.
- W3003325360 startingPage "1259" @default.
- W3003325360 abstract "Chemical processes in solution are influenced by microheterogeneity (MH), where two liquids seem to be mixed in a macroscopic scale but are microscopically inhomogeneous. We have investigated one of the simplest MH systems, aqueous acetonitrile solution, using soft X-ray absorption spectroscopy (XAS). Molecular interactions of acetonitrile were revealed by C and N K-edge XAS at different concentrations, and those of solvent water were separately revealed by O K-edge XAS. The energy shift of the C≡N π* peak at the C K-edge shows three characteristic concentration regions and a phase-transition-like behavior between them. By comparing the energy shifts in XAS spectra with ab initio quantum chemical inner-shell calculations, we have determined local structures of acetonitrile-water mixtures in three concentration regions and found that the dipole interaction between acetonitrile and water is the key structure to emerge the MH state in the middle concentration region." @default.
- W3003325360 created "2020-02-07" @default.
- W3003325360 creator A5031874578 @default.
- W3003325360 creator A5062507170 @default.
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- W3003325360 date "2020-01-28" @default.
- W3003325360 modified "2023-10-17" @default.
- W3003325360 title "Microheterogeneity in Aqueous Acetonitrile Solution Probed by Soft X-ray Absorption Spectroscopy" @default.
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- W3003325360 doi "https://doi.org/10.1021/acs.jpcb.0c00551" @default.
- W3003325360 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31990199" @default.
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