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- W3003384894 abstract "The shutting effect in lithium-sulfur (Li-S) batteries hinders their widespread application, which can be restrained effectively by a modified separator. In this work, a composite of reduced graphene oxide and beta-phase TiO2 nanoparticles (RGO/TiO2(B)) is designed as a separator modification material for improving the electrochemical behavior of Li-S batteries. The TiO2(B) nanoparticles are in situ prepared and tightly adhere to the RGO layer. A series of examinations demonstrated that the RGO/TiO2(B)-coated separator efficiently inhibits the polysulfide shuttling phenomenon by the cooperative effect of physical adsorption and chemical binding. Specifically, as modified separators, a comparison between TiO2(B) and anatase TiO2(A) each composited with RGO has been conducted. The TiO2(B) sample not only exhibits a superior blocking character of migrating polysulfides, but also enhances battery electrochemical kinetics by fast Li ion diffusion." @default.
- W3003384894 created "2020-02-07" @default.
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- W3003384894 date "2020-01-01" @default.
- W3003384894 modified "2023-10-14" @default.
- W3003384894 title "Reduced graphene oxide/TiO<sub>2</sub>(B) nanocomposite-modified separator as an efficient inhibitor of polysulfide shuttling in Li–S batteries" @default.
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- W3003384894 doi "https://doi.org/10.1039/c9ra10185c" @default.
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