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- W3003399774 abstract "Abstract Herein, we employed the conductometric measurement technique for the estimation of the interaction between two oppositely charged surfactants (anionic, sodium dodecyl sulfate [SDS] and tetradecyltrimethylammonium bromide [TTAB]) in two chloride (NaCl/NH 4 Cl) salts in the range of temperatures from 298.15 to 318.15 K. The deviation of experimental critical micelle concentration ( cmc ) from the corresponding ideal values of cmc ( cmc id ), the values of interaction parameters ( β ), and activity coefficients ( f 1 and f 2 ) of the components reveal the existence of the interaction amongst the investigated components. The attained cmc values for SDS/SDS + TTAB decline with the rise of temperature in H 2 O/electrolytes medium. The reduction of cmc in the presence of electrolytes reveals the facilitated micellization in the electrolyte medium. The assessed values of the micellar mole fraction of TTAB ( X 1 ) obtained from theoretical models signify the significant contribution of TTAB in SDS + TTAB mixed micellization. The estimated negative values of free energy ( ) and excess free energy ( ΔG ex ) of micellization reveal that micellization is spontaneous and mixed micelles are extra stable than distinct micelle, respectively. The enthalpy ( ) and entropy ( ) in addition transfer energies of micellization were also evaluated and explained thoroughly." @default.
- W3003399774 created "2020-02-07" @default.
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- W3003399774 date "2020-01-28" @default.
- W3003399774 modified "2023-09-27" @default.
- W3003399774 title "Investigation of mixed micellization study of sodium dodecyl sulfate and tetradecyltrimethylammonium bromide mixtures at different compositions: Effect of electrolytes and temperatures" @default.
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- W3003399774 doi "https://doi.org/10.1002/poc.4047" @default.
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