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- W3003772911 abstract "We report the solid-phase synthesis of N,N′-di(acylamino)-2,5-diketopiperazine, an acylhydrazide-based conformationally rigid 2,5-DKP scaffold having exocyclic N–N bonds. We also show that different combinations of acylhydrazides, carbazates, semicarbazides, amino acids, and primary amines can be used to synthesize a highly diverse collection of hybrid DKP molecules via the solid-phase submonomer synthesis route. Finally, we show incorporation of a methyl substituent in one of the carbon atoms of the DKP ring to generate chiral daa- and hybrid-DKPs without compromising the synthetic efficiency." @default.
- W3003772911 created "2020-02-07" @default.
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- W3003772911 date "2020-01-31" @default.
- W3003772911 modified "2023-10-13" @default.
- W3003772911 title "Solid-Phase Synthesis of Hybrid 2,5-Diketopiperazines Using Acylhydrazide, Carbazate, Semicarbazide, Amino Acid, and Primary Amine Submonomers" @default.
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- W3003772911 doi "https://doi.org/10.1021/acs.joc.9b02083" @default.
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