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• W3004010432 endingPage "4250" @default.
• W3004010432 startingPage "4246" @default.
• W3004010432 abstract "The radical-radical coupling reaction is an important synthetic strategy. In this study, the iron-catalyzed radical-radical cross-coupling reaction based on the decarboxylation of keto acids and decarbonylation of aliphatic aldehydes to obtain valuable aryl ketones is reported for the first time. Remarkably, when tertiary aldehydes were used as carbonyl sources, ketone esters were selectively obtained instead of ketones. The gram-scale preparation of aryl ketone through this strategy was easily achieved by using only 3 mol % of the iron catalyst. As a proof-of-concept, the bioactive molecule flurprimidol was synthesized in two steps by using this strategy." @default.
• W3004010432 created "2020-02-07" @default.
• W3004010432 creator A5019908354 @default.
• W3004010432 creator A5035405912 @default.
• W3004010432 creator A5041416876 @default.
• W3004010432 creator A5052274720 @default.
• W3004010432 creator A5077185196 @default.
• W3004010432 creator A5088322277 @default.
• W3004010432 date "2020-03-03" @default.
• W3004010432 modified "2023-10-14" @default.
• W3004010432 title "Iron‐Catalyzed Cleavage Reaction of Keto Acids with Aliphatic Aldehydes for the Synthesis of Ketones and Ketone Esters" @default.
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