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- W3004407890 abstract "Abstract GCn and GCnCG, where n = (G2AG4AG2), fold into well-defined, dimeric G-quadruplexes with unprecedented folding topologies in the presence of Na+ ions as revealed by nuclear magnetic resonance spectroscopy. Both G-quadruplexes exhibit unique combination of structural elements among which are two G-quartets, A(GGGG)A hexad and GCGC-quartet. Detailed structural characterization uncovered the crucial role of 5′-GC ends in formation of GCn and GCnCG G-quadruplexes. Folding in the presence of 15NH4+ and K+ ions leads to 3′–3′ stacking of terminal G-quartets of GCn G-quadruplexes, while 3′-GC overhangs in GCnCG prevent dimerization. Results of the present study expand repertoire of possible G-quadruplex structures. This knowledge will be useful in DNA sequence design for nanotechnological applications that may require specific folding topology and multimerization properties." @default.
- W3004407890 created "2020-02-07" @default.
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- W3004407890 date "2020-01-30" @default.
- W3004407890 modified "2023-10-16" @default.
- W3004407890 title "GC ends control topology of DNA G-quadruplexes and their cation-dependent assembly" @default.
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- W3004407890 doi "https://doi.org/10.1093/nar/gkaa058" @default.
- W3004407890 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7049726" @default.
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- W3004407890 hasPublicationYear "2020" @default.
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