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• W3004508014 abstract "Abstract Aprotic ionic polymers containing trimethylsilylmethyl‐substituted imidazolium structures are synthesized using free radical polymerization of monomers comprising a vinyl group either at the cation or at the anion. Bulk polymerization is used for the room temperature ionic liquid monomer 1‐trimethylsilylmethyl‐3‐vinylimidazolium bis(trifluoromethylsulfonyl)imide. In contrast to this, solution polymerization is applied for 1‐trimethylsilylmethyl‐3‐methylimidazolium p ‐styrene sulfonate because this monomer undergoes self‐polymerization during melting at a higher temperature than selected for bulk polymerization. Glass transition temperature ( T g ) of the ionic polymers and intrinsic viscosity measurements indicate differences between these polymers, which are composed either of a polycation with a trimethylsilylmethyl substituent at each vinylimidazolium segment of the polymer chain and mobile bis(trifluoromethylsulfonyl)imide (NTf 2 − ) anions or a polyanion containing p ‐styrene sulfonate segments and mobile 1‐trimethylsilylmethyl‐3‐methylimidazolium cations. The new aprotic ionic polymers containing trimethylsilylmethyl substituents may be interesting for application in adhesive, interlayer and membrane manufacturing." @default.
• W3004508014 created "2020-02-14" @default.
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• W3004508014 creator A5032081958 @default.
• W3004508014 date "2020-02-08" @default.
• W3004508014 modified "2023-10-02" @default.
• W3004508014 title "Synthesis of ionic polymers by free radical polymerization using aprotic trimethylsilylmethyl‐substituted monomers" @default.
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• W3004508014 doi "https://doi.org/10.1002/pol.20190310" @default.
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