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- W3004526968 endingPage "124389" @default.
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- W3004526968 abstract "High photo-catalytic activity and stable recycling performance under high humidity are main hindering factors in practical applications of metal organic frameworks (MOFs) for volatile organic compounds (VOCs) degradation. In-situ co-doping strategy of pyrrolic N/Zn was proposed to enhance surface charge separation and cycling stability of MIL-125(Ti) for degradation of vaporous acetaldehyde under highly humid conditions. Characterizations results show that pyrrolic N/Zn co-doped MIL-125(Ti) exhibited an integrated crystal structure and high surface area (1415 m2/g). The constructed Ti/Zn-N/O clusters narrowed band gap (from 3.40 to 1.85 eV) of MIL-125(Ti) and boosted electron conductivity. Also, it was proved to enhance surface alkalinity and hydrophobicity of MIL-125(Ti), which would strengthen MOFs selective adsorption towards CH3CHO and accelerated the transfer of degradation product CO2 from catalytic active sites in MIL-125(Ti) under high humidity. As a result, synergistic effect of N/Zn co-doping exhibited an enhanced the ability of activating oxygen and H2O molecules into superoxide radical (O2−) and hydroxy radical (OH), showing 10 times faster reaction kinetics for CH3CHO degradation under humid air compared to MIL-125(Ti). Moreover, co-dopant of N/Zn into MIL-125(Ti) has significantly promoted the recycling stability of MIL-125(Ti) under high humidity. According to the work, co-dopant elemental strategy to modify MOF surface can provide the synergistic effect for efficient degradation of aldehyde VOCs under humid conditions." @default.
- W3004526968 created "2020-02-14" @default.
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- W3004526968 date "2020-05-01" @default.
- W3004526968 modified "2023-10-13" @default.
- W3004526968 title "Enhanced moisture-resistance and excellent photocatalytic performance of synchronous N/Zn-decorated MIL-125(Ti) for vaporous acetaldehyde degradation" @default.
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- W3004526968 cites W1963662065 @default.
- W3004526968 cites W1966484307 @default.
- W3004526968 cites W1973914061 @default.
- W3004526968 cites W1979492569 @default.
- W3004526968 cites W1982540043 @default.
- W3004526968 cites W1989827560 @default.
- W3004526968 cites W1993054776 @default.
- W3004526968 cites W2001283055 @default.
- W3004526968 cites W2014947190 @default.
- W3004526968 cites W2021891358 @default.
- W3004526968 cites W2027464856 @default.
- W3004526968 cites W2029083396 @default.
- W3004526968 cites W2035771801 @default.
- W3004526968 cites W2036432526 @default.
- W3004526968 cites W2039317021 @default.
- W3004526968 cites W2059726151 @default.
- W3004526968 cites W2064069351 @default.
- W3004526968 cites W2072181067 @default.
- W3004526968 cites W2076270109 @default.
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- W3004526968 cites W2089782593 @default.
- W3004526968 cites W2090133266 @default.
- W3004526968 cites W2111062994 @default.
- W3004526968 cites W2124309252 @default.
- W3004526968 cites W2125521188 @default.
- W3004526968 cites W2127360275 @default.
- W3004526968 cites W2130822317 @default.
- W3004526968 cites W2141939342 @default.
- W3004526968 cites W2142797228 @default.
- W3004526968 cites W2156125813 @default.
- W3004526968 cites W2163335877 @default.
- W3004526968 cites W2174042645 @default.
- W3004526968 cites W2195610632 @default.
- W3004526968 cites W2227237104 @default.
- W3004526968 cites W2254545434 @default.
- W3004526968 cites W2283564633 @default.
- W3004526968 cites W2313173854 @default.
- W3004526968 cites W2322562148 @default.
- W3004526968 cites W2325445855 @default.
- W3004526968 cites W2492204164 @default.
- W3004526968 cites W2524047915 @default.
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- W3004526968 cites W2568047343 @default.
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- W3004526968 cites W2626732819 @default.
- W3004526968 cites W2626900885 @default.
- W3004526968 cites W2754702138 @default.
- W3004526968 cites W2765132906 @default.
- W3004526968 cites W2769803873 @default.
- W3004526968 cites W2772841624 @default.
- W3004526968 cites W2790496599 @default.
- W3004526968 cites W2791290037 @default.
- W3004526968 cites W2791518892 @default.
- W3004526968 cites W2792189574 @default.
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- W3004526968 cites W2802453187 @default.
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- W3004526968 doi "https://doi.org/10.1016/j.cej.2020.124389" @default.
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