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• W3004798466 abstract "Metal nanoparticles are synthesized via various methods and have found many applications in areas such as sensing, electronics and catalysis. Light induced formation of noble metal nanoparticles, especially platinum, in solution or loaded on semiconductor surfaces, is an established practice in photocatalysis. Nevertheless, preparation of catalytically-active non-precious metal nanoparticles via photo-reduction still have room to be further explored. Here, we report a visible light driven system that can coordinate photo-reduction of CuSO4 to selectively prepare Cu2O or Cu nanoparticles, while at the same time, mediating efficient hydrogen production with in situ generating Cu catalyst without further need to add any components. The Cu2O and Cu nanoparticles in situ generated are crystalline in nature and can perform as pre-catalyst (Cu2O) or catalyst (Cu) to catalyze hydrogen production when reincorporated into the same photo-reduction system with organic photosensitizers. Our work offers an exploratory pathway to prepare target metal nanoparticles while provides some insight into harnessing solar energy for multi-functional purposes." @default.
• W3004798466 created "2020-02-14" @default.
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• W3004798466 date "2020-01-01" @default.
• W3004798466 modified "2023-10-17" @default.
• W3004798466 title "Visible light driven photo-reduction of Cu²⁺ to Cu₂O to Cu in water for photocatalytic hydrogen production" @default.
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• W3004798466 doi "https://doi.org/10.1039/c9ra09590j" @default.
• W3004798466 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35497418" @default.
• W3004798466 hasPublicationYear "2020" @default.
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